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The Luca battle scene is the coolest one I've seen in an RPG:
clarifications on Gechmir's description:
Your party ambushes him, after Leon Silverberg betrays him, iirc, and you have to fight him three times, with different teams. Everytime it's one of the tougher battles in the game, since he has such a high defense.
After that he escapes, and is lured to an open place. When he touches a decoy planted there by your army, he releases some fluorescent dust, giving your archers the chance to shoot him. He still doesn't give up, and you have to fight him one on one, finally killing him.